WANG Kai
,
XU Tingdong
,
SHAO Chong
,
YANG Chun
钢铁研究学报(英文版)
The data obtained by bending tests for intergranular embrittlement after 45 h and 450 h exposure to Strauss solution have been reported for 304 stainless steel. The results show that an embrittlement peak appears at 650 ℃ for all samples quenched from 1260 ℃ and then sensitized for 150 h at 480, 565, 650, 730, 815 and 900 ℃ respectively. The temperature corresponding to the embrittlement peak is decreased to 565 ℃ when the sensitizing time is prolonged to 1500 h. In this paper, these data are analyzed with an isothermal kinetic model of nonequilibrium grain boundary segregation, indicating that the embrittlement peak is related to the critical time for nonequilibrium grain boundary segregation of sulfur.
关键词:
stainless steel
,
intergranular corrosion
,
nonequilibrium segregation
,
grain boundary
,
sulfur
WANG Kai
,
SI Hong
,
YANG Chun
,
XU Tingdong
钢铁研究学报(英文版)
In virtue of Auger electron spectroscopy, the grain-boundary concentrations of phosphorus in Ni-Cr-Fe superalloy after solution-treated at 1180℃ for 45 min are measured, the results show that a peak of phosphorus concentration occurs at about 180 min during isothermal ageing at 500℃, and a maximum concentration of phosphorus appears also at about 500℃ for all specimens aged for 20 min at temperatures of 200,400,500,700 and 800℃. The results are analysed with the laws of non-equilibrium grain-boundary segregation. It is found from the analysis that peaks are relative to critical time for non-equilibrium grain-boundary segregation of phosphorus.
关键词:
Non-equilibrium segregation;Grain boundaries;Phosphorus;Nickel based superalloys
陶明慧
,
张星祥
,
张宇
,
任建岳
,
李新娥
液晶与显示
doi:10.3788/YJYXS20112601.0105
针对某航空相机的设计要求,提出了一种可行的多模式驱动时序设计方法.采用柯达公司的KAI-2093行间转移型面阵CCD传感器.结合它的结构特点和双通道数据传输的思想分析了传感器驱动时序关系,提出了3种驱动模式:binning、no-binning和TDI模式.以Ahera公司的FPGA芯片EP1C6Q240作为时序发生器并实现数据的缓存和拼接,从而实现了时序发生器与数据处理器的一体化设计.在QUARTUSII7.0开发环境下采用VHDL语言编程,通过Modelsim AE6.1b实现数据缓存器的仿真.实测结果表明,所设计的驱动时序满足KAI-2093的时序要求,binning模式下帧频可达60帧/s,120帧/s等,满足高速跟踪要求;no-binning模式下全帧输出帧频可达30帧/s;TDI模式下能保证CCD长时间工作而不影响成像质量,该没计方法提高了系统的集成度和抗干扰能力.
关键词:
航空相机
,
binning模式
,
TDI模式
,
数据缓存
,
数据拼接
,
FPGA
Journal of Materials Research
The morphology of the dark and bright regions observed by transmission electron microscopy for the Zr(64.13)Cu(15.75)Ni(10.12)Al(10) bulk metallic glass strongly depends on the ion beam parameters used for ion milling. This indicates that the ion beam could introduce surface fluctuation to metallic glasses during ion milling.
关键词:
room-temperature
材料科学技术（英）
The effect of interstitial hydrogen on the cohesion of the Al Sigma=11(113) grain boundary (GB) is investigated based on the thermodynamic model of Rice-Wang using the first-principles density function calculation. The results indicate that interstitial H behaves as an embrittler from "strengthening energy" analysis. The reduced GB cohesion due to the presence of H at the GB is attributed to the low affinity between H and Al, and the weakened bonding of Al atomic pairs perpendicular to GB plane.
关键词:
hydrogen;grain boundary;Al-Mg alloys;pseudopotentials;1st-principles
Xiaoguang LIU
,
Xiaowei WANG
材料科学技术（英）
The effect of interstitial hydrogen on the cohesion of the Al ∑=11(113) grain boundary (GB) is investigated based on the thermodynamic model of Rice-Wang using the first-principles density function calculation. The results indicate that interstitial H behaves as an embrittler from "strengthening energy" analysis. The reduced GB cohesion due to the presence of H at the GB is attributed to the low affinity between H and Al, and the weakened bonding of Al atomic pairs perpendicular to GB plane.
关键词:
Hydrogen
,
null
,
null
Physical Review B
By use of the linear-combination-of-atomic-orbital (LCAO) method for a cluster model, we studied the electronic structure of gamma-from Sigma 11 [1 (1) over bar0](11 (3) over bar) grain boundary doping with N and Mn atoms. The effect of the segregation on the cohesion of the grain boundary is investigated based on the Rice-Wang thermodynamic model. It is found that N could not only largely enhance the cohesion of the grain boundary but also eliminate the detrimental effect of Mn. The cosegregation effect of Mn and N on the cohesion of the grain boundary depends on where they segregate. Nitrogen could be reliably used in alloyed steels as an efficient strengthening element.
关键词:
electronic-structure;phosphorus segregation;stainless-steel;embrittlement;austenite;nitrogen;boron;impurities;fracture;metals
Journal of Physics and Chemistry of Solids
The layered ternary ceramics Ti3SiC2 and Ti3AlC2 are isostructural and can form Ti3Si1-xAlxC2 solid solutions combining the advanced properties of both compounds [H.B. Zhang, Y.C. Zhou, Y.W. Bao, M.S. Li, Improving the oxidation resistance of Ti3SiC2 by forming a Ti3Si0.90Al0.1C2 solid solution, Acta Mater. 52 (2004) 3631-3637; E.D. Wu, J.Y. Wang, H.B. Zhang, Y.C. Zhou, K. Sun, Y.J. Xue, Neutron diffraction studies of Ti3Si0.9Al0.1C2 compound, Mater. Lett. 59 (2005) 2715-2719; J.Y. Wang, Y.C. Zhou, First-principles study of equilibrium properties and electronic structure of Ti3Si0.75Al0.25C2 solid solution, J. Phys.: Condens. Matter 15 (2003) 5959-5968; Y.C. Zhou, J.X. Chen, J.Y. Wang, Strengthening of Ti3AlC2 by incorporation of Si to form Ti3Al1-xSixC2 solid solutions, Acta. Mater. 54 (2006) 1317-1322]. In the present work, the solid solutions of Ti3Si1-xAlxC2 (x = 0, 0.25, 0.33, 0.5, 0.67, 0.75, 1) are investigated by first-principle calculations based on pseudo-potential plan-wave method within the density functional theory framework. The results show that as Al content increases in the solid solution, all the bonds have weakened to certain extents, which lead to an unstable structure both energetically and geometrically. The calculated results are compared and discussed with the reported data for the Ti3Si1-xAlxC2 solid solutions. (c) 2007 Elsevier Ltd. All rights reserved.
关键词:
ceramics;ab initio calculations;electronic structure;electrical;conductivity;oxidation behavior;mechanical-properties;ti3sic2;temperature;ti3alc2;air;si
